LESSON 2.4CHEMISTRY I: GENERAL CHEMISTRY

ELECTRON CONFIGURATION NOTATION

In lesson 2.3 we learned the rules for filling orbitals. Now we put them into writing — the precise shorthand chemists use to record exactly where every electron in an atom lives.

READING & WRITING THE NOTATION

An electron configuration lists each occupied subshell in order, with a superscript showing how many electrons it contains. The format is:

FORMAT

n++e⁻
n = principal quantum number (shell) = subshell letter (s / p / d)superscript = electron count

For example, carbon (Z=6) has 6 electrons to place. The first 2 go into 1s, the next 2 fill 2s, and the final 2 begin filling 2p:

CARBON (Z=6)

1s22s22p2→ 6 electrons total ✓

Step through the explorer below to see how configurations build up across the first 36 elements.

// INTERACTIVE — ELECTRON CONFIGURATION EXPLORER

CZ = 6

CARBON

P-BLOCK

ORBITAL DIAGRAM

1s
2/2e⁻
2s
2/2e⁻
2p
2/6e⁻

FULL CONFIGURATION

1s22s22p2

ABBREVIATED

[He]2s22p2
s-subshell · 1 orbital · max 2e⁻
p-subshell · 3 orbitals · max 6e⁻
d-subshell · 5 orbitals · max 10e⁻
↑↓ = one electron per arrow (Hund's rule)
6 / 36

THE s/p/d BLOCKS

The shape of the periodic table is not arbitrary — it directly reflects which subshell is being filled as you move across each period. This divides the table into named blocks:

S-BLOCK

Groups 1–2, plus He

Outermost electrons fill an s subshell

H, He, Li, Na, K, Ca — the alkali and alkaline earth metals (plus hydrogen and helium).

P-BLOCK

Groups 13–18 (except He)

Outermost electrons fill a p subshell

B through Ne, Al through Ar, Ga through Kr — includes nonmetals, metalloids, and noble gases.

D-BLOCK

Groups 3–12

The (n−1)d subshell is being filled

Sc through Zn, Y through Cd — the transition metals. Note 4s fills before 3d.

F-BLOCK

Lanthanides & actinides (rows 6–7, detached)

The (n−2)f subshell is being filled

Ce–Lu, Th–Lr — rare earths and heavy radioactive elements.

The block an element belongs to tells you which subshell its highest-energy electrons occupy. This is directly related to its chemical behaviour — the valence electrons we studied in lesson 2.2 are always the outermost s and p electrons (for s and p block elements), which is why Group number predicts valence electron count so cleanly.

ABBREVIATED NOTATION

Writing out the full configuration for every element gets tedious fast. Because noble gases have completely filled, stable electron arrangements, chemists use them as shorthand. Instead of writing everything from 1s onward, you write the previous noble gas in square brackets, then list only the electrons added after it.

EXAMPLES

Sodium Na Z=11

1s22s22p63s1
[Ne]3s1

Chlorine Cl Z=17

1s22s22p63s23p5
[Ne]3s23p5

Iron Fe Z=26

1s22s22p63s23p63d64s2
[Ar]3d64s2

The abbreviated form is what you'll most often see in textbooks and exams. It strips away the stable, chemically inert core and highlights only the electrons that actually participate in bonding — exactly the valence electrons we studied in lesson 2.2.

PRACTICE: ORBITAL RUSH

Place electrons onto a 3D atom one spin at a time — applying Aufbau order and Hund's rule from memory. Play in Normal mode for a relaxed no-timer challenge, or switch to Rush mode and race the 60-second clock. Three lives in either mode.

// MINIGAME — ORBITAL RUSH

ORBITAL RUSH

ELECTRON PLACEMENT CHALLENGE

1.A random element appears. Place its electrons onto the atom one at a time.
2.Pick ↑ or ↓ from the buckets. Either spin is fine for the first electron in a subshell — just stay consistent.
3.Hund's rule: all singly-occupied orbitals must match your chosen spin before any pairing begins.
4.Wrong spin = lose a life. Correct = electron appears on the glowing ring.
5.+10 pts per element completed without error.

SELECT MODE

No time limit — 3 lives. Take your time.

UP NEXT

We now know exactly where every electron in an atom lives. In lesson 2.5 we will see how these configurations drive periodic trends — predictable patterns in atomic size, ionization energy, and electronegativity that reveal the hidden architecture of the table.

READ LESSON 2.5 →